If you need to open two or more skype accounts at the same time on same PC just follow my steps. This is very easy to done. You can simply open skype from start menu or desktop. But if you try to open new one skype (Just like other programs) again, nothing! This will unable to open new one.
Now go to your skype installation folder. C:\Program Files\Skype\Phone
Right click the skype executable (Skype.exe) and make a shortcut to desktop.
*Note that do not make shortcut from start menu.
Now go to the desktop right click the skype shortcut click properties go to shortcut tab and type this in target field.
“C:\Program Files\Skype\Phone\Skype.exe” /secondary
Then press Apply and Ok.
Now you can open multiple skype account at the same time using this shortcut.
Nice post. Thank you!